Calcule el pH de: a. HCl 0.050M b. HC2H3O2 0.070M ; (Ka=1.8 x10-5 ) c. NaOH 0.80M d. Ba(OH)2 0.30M
Respuestas
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2
Datos :
PH = ?
Parte a .
HCL 0.050 M
como el acido esta ionizado α = 1 y ( H₃O ⁺) = M * α
= 1 * 0.1
= 0.1
PH = -log ( H₃O ⁺) = - log ( 0.1) = 1.30
parte b
0.070 M HC₂H₃O₂ Ka = 1.8 * 10 ⁻⁵
CH₃- COOH +H₂O ⇔ H₃O⁺ +CH₃-COO⁻
Ka = (H₃O⁺) * (H-COO⁻)/(CH₃-COO⁻)
(H₃O⁺)=(CH₃-COO⁻) M * α
(CH₃-COO⁻) =M
Ka = (M * α ) * (M * α)/M
(M * α ) ² =Ka * M
(M* α) = ( H₃O⁺) = √(Ka * M)
= √(1.8 * 10⁻⁵ * 0.070)
= 1.122 * 10⁻³
PH = - log (H₃O⁺) =
= - log ( 1.122 *10 ⁻³)
PH = 2.94
Parte c
NaOH (OH⁻) = 0.80
POH = - log (OH⁻) = - log ( 0.80) = 0.0969
PH + POH = 14
PH = 14 - POH = 14 - 0.0969 = 13.90
Parte d
Ba (OH )₂ ( OH⁻)=0.30 M
POH =-log ( OH⁻) = - log ( 0.30) = 0.5228
PH = 14 - POH = 14 - 0.5228 = 13.47
PH = ?
Parte a .
HCL 0.050 M
como el acido esta ionizado α = 1 y ( H₃O ⁺) = M * α
= 1 * 0.1
= 0.1
PH = -log ( H₃O ⁺) = - log ( 0.1) = 1.30
parte b
0.070 M HC₂H₃O₂ Ka = 1.8 * 10 ⁻⁵
CH₃- COOH +H₂O ⇔ H₃O⁺ +CH₃-COO⁻
Ka = (H₃O⁺) * (H-COO⁻)/(CH₃-COO⁻)
(H₃O⁺)=(CH₃-COO⁻) M * α
(CH₃-COO⁻) =M
Ka = (M * α ) * (M * α)/M
(M * α ) ² =Ka * M
(M* α) = ( H₃O⁺) = √(Ka * M)
= √(1.8 * 10⁻⁵ * 0.070)
= 1.122 * 10⁻³
PH = - log (H₃O⁺) =
= - log ( 1.122 *10 ⁻³)
PH = 2.94
Parte c
NaOH (OH⁻) = 0.80
POH = - log (OH⁻) = - log ( 0.80) = 0.0969
PH + POH = 14
PH = 14 - POH = 14 - 0.0969 = 13.90
Parte d
Ba (OH )₂ ( OH⁻)=0.30 M
POH =-log ( OH⁻) = - log ( 0.30) = 0.5228
PH = 14 - POH = 14 - 0.5228 = 13.47
anais930:
muchas gracias bendiciones
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